The Baeyer–Villiger Oxidation of Cycloketones Using Hydrogen Peroxide as an Oxidant

Baeyer–Villiger oxidation can synthesize a series of esters or lactones that have essential application value but are difficult to be synthesized by other methods. Cycloketones oxidized using molecular oxygen, peroxy acids, hydrogen peroxide as an oxidant. Hydrogen is one the environmental oxidants. Because weak ability peroxide, Bronsted acids and Lewis used catalysts activate carbonyl ketones increase nucleophilic performance peroxide. The catalytic mechanisms differ in cyclohexanone with aqueous solution